First-principles calculation of field emission from adsorbed atom on metallic electrode

We present calculations of field emission current using the first-principles recursion-transfer-matrix (RTM) method with nonlocal pseudopotentials. The original boundary condition of the RTM method is modified to express a constant electric field deep into a vacuum region. We analyze field emission from an Al atom adsorbed on a metallic electrode and show the microscopic distributions of the electron emission current and the potential barrier for the system.