Adsorption structure of phenylphosphonic acid on an alumina surface

The adsorption structure of phenylphosphonic acid (PPOA) on an alumina surface was investigated as a function of exposure and temperature using infrared reflected absorption spectroscopy (IRAS) and a Kelvin probe. The alumina surface was held at room temperature during deposition. At monolayer adsorption, Psingle bondO and Phenyl-P bands are observed, which indicate the creation of Psingle bondOsingle bondAl bonds. The aromatic ring plane is positioned perpendicular to the surface, i.e. deprotonated PPOA stands vertically on the surface. At multilayer adsorption, Pdouble bond; length as m-dashO and Psingle bondOH bands appear in the spectra. The multilayer PPOA film starts to desorb at 400 K. From 400 to 700 K, the IRAS spectra are similar to the monolayer spectrum, indicating that the multilayer structure reverses to the monolayer-like PPOA adlayer by heating. The acid molecules start to desorb at 700 K.