• Title of article

    A new model for the inference of population characteristics from experimental data using uncertainties: Part II. Application to censored datasets Original Research Article

  • Author/Authors

    Wim P. Cofino، نويسنده , , Ivo H.M. van Stokkum، نويسنده , , Jaap van Steenwijk، نويسنده , , David E. Wells، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    9
  • From page
    31
  • To page
    39
  • Abstract
    This paper extends a recent report on a model to establish population characteristics to include censored data. The theoretical background is given. The application given in this paper is limited to left-censored data, i.e. less than values, but the principles can also be adopted for other types of censored data. The model gives robust estimates of population characteristics for datasets with complicated underlying distributions including less than values of different magnitude and less than values exceeding the values of numerical data. The extended model is illustrated with simulated datasets, data from interlaboratory studies and temporal trend data on dissolved cadmium in the Rhine river. The calculations confirm that inclusion of left-censored values in the computation of population characteristics improves assessment procedures.
  • Keywords
    LOD , LOQ , Less than values , mean , Standard deviation , , Censored data , Left-censored data , Maximum likelihood estimation (MLE) , Detection limit , Robust statistics , Interlaboratory studies , Censored samples
  • Journal title
    Analytica Chimica Acta
  • Serial Year
    2005
  • Journal title
    Analytica Chimica Acta
  • Record number

    1034591