Title of article
Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides
Author/Authors
Dadrass، Alireza نويسنده Faculty of Chemistry, Urmia University, 57159, Urmia, Iran , , Ebrahimnezhad، Shahla نويسنده Faculty of Chemistry, Urmia University, Urmia 57154, Urmia, Iran , , Pourmirza، Mahsa نويسنده Faculty of Chemistry, Urmia University, Urmia 57154, Urmia, Iran , , Poursattar Marjani، Ahmad نويسنده ,
Issue Information
فصلنامه با شماره پیاپی 10 سال 2014
Pages
6
From page
103
To page
108
Abstract
The novel ?-phosphorus labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone (PTTPPY) is prepared by the reaction of 2-bromo-1-(p-tolyl)ethanone with tri-p-tolylphosphine in chloroform as solvent. The complexes of the type [HgX2(p-tolyl)3PCHCOC6H4CH3)] (X = Cl, Br and I) are prepared by the reaction of title ylide with mercury(II) halides in good yields, using methanol as solvent. The final products were characterized by IR, 1H, 13C, 31P NMR spectroscopic methods and microanalysis.
Journal title
Current Chemistry Letters
Serial Year
2014
Journal title
Current Chemistry Letters
Record number
1043038
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