Influence of coherent structures on mass transfer near stagnation region in agitated small tanks

Electrochemical method is applied to study coherent structures in a complex three-dimensional flow generated by a rotating magnetic rod. In order to detect these structures, the power spectral density (PSD) analysis of the limiting diffusion current fluctuations is provided. This analysis reveals the existence of resonance frequencies when the probe is located in the very vicinity of the stirrer. The main resonance is related to the mechanical excitation frequency. The detailed analysis of the PSD curves points out some mechanisms of development of turbulence as sub-harmonics and non-linear interactions. For different locations of the probe and different angular rates of the stirrer Ω, a similarity of the energy repartition is obtained when the PSD is plotted versus the adimensional frequency f/Ω. Flow visualization by laser tomography is also provided and the local secondary flow past the electrode probe is sketched. The laser Doppler velocimetry (LDV) at a given location in a horizontal z-plane indicates a tornado wise mean flow structure.