• Title of article

    An Easy Deoxygenation of Conjugated Epoxides

  • Author/Authors

    Giuliana Righi، نويسنده , , Paolo Bovicelli، نويسنده , , Anna Sperandio، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2000
  • Pages
    5
  • From page
    1733
  • To page
    1737
  • Abstract
    An easy and high yielding transformation of epoxyketones and phenyl substituted epoxides to trans olefins in a convergent diastereoselective process is reported. The method was applied to the selective C-25 hydroxy-functionalisation of 3-keto-Δ4-cholestan-3-one, a key intermediate for the synthesis of C-25 hydroxy vitamin D3.
  • Keywords
    oxiranes , Deoxygenation , Isomerisation
  • Journal title
    Tetrahedron
  • Serial Year
    2000
  • Journal title
    Tetrahedron
  • Record number

    1080652

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1080652