Title of article
The Phenylthiocyclopropylsilyl Group: a Useful Latent Hydroxy Group
Author/Authors
Rémy Angelaud، نويسنده , , Yannick Landais، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
12
From page
2025
To page
2036
Abstract
The α-dimethyl(1-phenylthio)cyclopropylsilyl group was used as a new masked hydroxy group. Three procedures have been devised to allow the oxidation of this silicon group in the presence of various functionalities. The desired alcohols are obtained in high yields with retention of configuration at the carbon centre.
Keywords
Oxidation , silicon and compounds , Pummerer reactions , sulfoxides
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1080681
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