Title of article
The Regiochemistry of Carbenoid Insertion into Zirconacycles
Author/Authors
George J. Gordon، نويسنده , , Tim Luker، نويسنده , , Mark W. Tuckett، نويسنده , , Richard J. Whitby، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
17
From page
2113
To page
2129
Abstract
The regioselectivity of insertion of lithium chloroallylides (allyl carbenoids) into a wide variety of unsymmetrical zirconacycles has been determined. In all but one case a single regioisomer was obtained. A combination of steric and electronic effects is needed to explain the results and imply that the carbenoid is acting predominantly as an electrophilic species. The first carbenoid insertion into a zirconacyclopentadiene is noted.
Keywords
carbenoid , Zirconium , zirconacycle , insertion reactions
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1080689
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