Title of article
A New Procedure for Construction of Oxocane and Oxonane Derivatives Based on Alkyne–Co2(CO)6 Complexes
Author/Authors
Chisato Mukai، نويسنده , , Haruhisa Yamashita، نويسنده , , Tetsuya Ichiryu، نويسنده , , Miyoji Hanaoka، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
7
From page
2203
To page
2209
Abstract
Treatment of 2-(3-hydroxy-5-phenylpent-4-yn-1-yl)-2-(trimethylsilylmethyl)tetrahydrofuran (18) with Co2(CO)8 gave the corresponding cobalt complex, which was subsequently exposed to methanesulfonyl chloride and triethylamine in methylene chloride at refluxing temperature to provide the oxocane derivative 20 in 72% yield. This method was found to be applicable for construction of the oxonane framework.
Keywords
oxepane , oxocane , oxonane
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1080698
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