Title of article
Palladium-Catalyzed Acetoxylation of Cyclic Allyl Phosphonates in the Presence of Isopentyl Nitrite and Using Molecular Oxygen as Final Oxidant
Author/Authors
Mireille Attolini، نويسنده , , Gilbert Peiffer، نويسنده , , Michel Maffei، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
2693
To page
2697
Abstract
The palladium-catalyzed acetoxylation of cyclic dialkyl allyl phosphonates is effected using palladium chloride as catalyst, in the presence of isopentyl nitrite in acetic acid under an oxygen atmosphere. The proposed mechanism for the reaction involves a palladium nitro–nitroso redox couple.
Keywords
3-acetoxy-1-alkenyl phosphonates , palladium-catalyzed acetoxylation , isopentyl nitrite , cyclic dialkyl allyl phosphonates
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1080748
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