Title of article
Synthesis of [3H2]-(11S,17R)-11,17-Dimethylhentriacontane: a Useful Tool for the Study of the Internalisation of Communication Pheromones of Ant Camponotus vagus
Author/Authors
Delphine Pempo، نويسنده , , Jean-Christophe Cintrat، نويسنده , , Jean-Luc Parrain، نويسنده , , Maurice Santelli، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
5493
To page
5497
Abstract
The convergent synthesis in high enantiomeric and diastereoisomeric purity of [3H2]-(11S,17R)-11,17-dimethylhentriacontane, a communication pheromone of ant Camponotus vagus is described. The stereogenic centres were introduced from commercially available (S)-citronellol and (R)-citronellal and the tritiation step was conducted in the last step of the synthesis with tritium gas over the Wilkinson catalyst.
Keywords
citronellol , citronellal , tritium , Pheromone , dimethylhentriacontane , Total synthesis
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081045
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