Title of article
Radical Cyclization in Heterocycle Synthesis. Part 9: A Novel Synthesis of Aminocyclitols and Related Compounds via Stannyl Radical Cyclization of Oxime Ethers Derived from Sugars
Author/Authors
Toshiko Kiguchi، نويسنده , , Kazumi Tajiri، نويسنده , , Ichiya Ninomiya، نويسنده , , Takeaki Naito، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
15
From page
5819
To page
5833
Abstract
Stannyl radical addition–cyclization of oxime ethers derived from d-glucose, d-galactose, and d-xylose proceeded smoothly to afford alkoxyamino alcohols which were effectively converted into two types of glycosidase inhibitors or its candidates such as aminocyclitols, 1-deoxynojirimycin, and 1-deoxygalactostatin via reductive ring-expansion of trans alkoxyamino alcohols.
Keywords
piperidines , Amino alcohols , radicals and radical reactions , ring transformations
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081078
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