Title of article
Trifluoromethanesulfonic Acid Catalyzed Novel Friedel–Crafts Acylation of Aromatics with Methyl Benzoate
Author/Authors
Je Pil Hwang، نويسنده , , G.K. Surya Prakash، نويسنده , , George A. Olah، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
7199
To page
7203
Abstract
Methyl benzoate, protolytically activated by superacidic trifluoromethanesulfonic acid, reacts with aromatic compounds to give benzophenone derivatives in good to excellent yields (70–93%). Even highly deactivated nitrobenzene as well as benzotrifluoride underwent smooth benzoylation under the reaction conditions to respective meta-substituted benzophenones.
Keywords
Methyl benzoate , trifluoromethanesulfonic acid , superelectrophilic activation , benzo-phenones , Benzoylation
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081218
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