Title of article
Diazo Decomposition in the Presence of Tributyltin Hydride. Reduction of α-Diazo Carbonyl Compounds
Author/Authors
Zhongping Tan، نويسنده , , Zhaohui Qu، نويسنده , , Xiao-Bei Chen، نويسنده , , Jianbo Wang ، Yan Yan ، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
7457
To page
7461
Abstract
The diazo group of a series of α-diazo carbonyl compounds can be reduced to the corresponding CH2 group by Bu3SnH under Cu(acac)2-catalytic or photochemical conditions. The mechanistic aspects of this reaction were investigated in some detail, and a possible reaction pathway was discussed.
Keywords
diazo compounds , carbene and carbenoids , Reduction
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081251
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