Title of article
Regioselective Synthesis of β- and γ-Thujaplicins
Author/Authors
Min Gyu Soung، نويسنده , , Masanao Matsui، نويسنده , , Takeshi Kitahara، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2000
Pages
5
From page
7741
To page
7745
Abstract
β-Thujaplicin (hinokitiol) 1 and γ-thujaplicin 2, as the first naturally occurring monocyclic tropolone, were regioselectively synthesized from (R)-(+)-limonene, by using different dienyl silyl ether intermediates, 7 and 10, in 18% overall yield via 11 steps and 22% overall yield via 10 steps, respectively.
Keywords
?-thujaplicin (hinokitiol) , ?-thujaplicin , thermodynamic dienyl silyl ether , Limonene
Journal title
Tetrahedron
Serial Year
2000
Journal title
Tetrahedron
Record number
1081283
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