Title of article
Functionalised organotitanium compounds: from lithium to titanium intermediates in chemoselective reactions with carbonyl compounds
Author/Authors
Isidro M Pastor، نويسنده , , Miguel Yus، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
6
From page
2365
To page
2370
Abstract
The reaction of functionalised organolithium compounds 1 with an equimolecular mixture of two carbonyl compounds in the presence of 2 equiv. of triisopropoxytitanium chloride can discriminate between aldehyde and ketone, the process being selective for aldehydes at room temperature. Electronic and steric effects have been observed for different aldehydes.
Keywords
Carbonyl compounds , functionalised organolithiums , organotitanium compounds
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1081815
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