• Title of article

    3,5-Dimethylpyrazolium fluorochromate(VI), C5H8N2H[CrO3F], (DmpzHFC): a convenient new reagent for oxidation of organic substrates

  • Author/Authors

    Upasana Bora Sinha، نويسنده , , Mihir K. Chaudhuri and Sahid Hussain ، نويسنده , , Deepa Dey، نويسنده , , Dipak Kalita، نويسنده , , Wancydora Kharmawphlang، نويسنده , , Gagan C Mandal، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    2445
  • To page
    2448
  • Abstract
    A new chromium(VI) reagent, 3,5-dimethylpyrazolium fluorochromate, C5H8N2H[CrO3F] (DmpzHFC), has been developed by reacting dmpz with CrO3 and aqueous HF for the selective oxidation of primary, secondary and allylic alcohols to the corresponding carbonyl compounds, polycyclic hydrocarbons to cyclic ketones and allylic Δ5-steroids to the corresponding α,β-unsaturated ketones.
  • Keywords
    Alcohols , polycyclic hydrocarbons , Oxidations , Chromium(VI) , ?5-steroids
  • Journal title
    Tetrahedron
  • Serial Year
    2001
  • Journal title
    Tetrahedron
  • Record number

    1081825