Title of article
New chiral phosphorus-containing dendrimers with ferrocenes on the periphery
Author/Authors
Cédric-Olivier Turrin، نويسنده , , Jérome Chiffre، نويسنده , , Jean-Claude Daran، نويسنده , , Dominique de Montauzon، نويسنده , , Anne-Marie Caminade، نويسنده , , Eric Manoury، نويسنده , , Gilbert Balavoine، نويسنده , , Jean-Pierre Majoral، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
16
From page
2521
To page
2536
Abstract
Four series of new chiral ferrocenyl dendrimers (up to the 11th generation) have been synthesised and fully characterised. Electrochemical studies have been carried out on these dendrimers. In every case, one single oxidation wave has been observed, corresponding to the independent oxidation of all the ferrocene groups to ferrocenium. The chiroptical properties of the different dendrimers have been studied: the molar rotation depends only on the number of stereogenic units, independently of the generation in all series of dendrimers.
Keywords
Phosphorus , Ferrocene , Dendrimer , Chirality
Journal title
Tetrahedron
Serial Year
2001
Journal title
Tetrahedron
Record number
1081834
Link To Document