• Title of article

    Reactions of acylsulfonium salts with unsaturated hydrocarbons

  • Author/Authors

    Valentine G. Nenajdenko، نويسنده , , Mikhail V. Lebedev، نويسنده , , Elisabeth S Balenkova، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    8
  • From page
    9017
  • To page
    9024
  • Abstract
    The reactions of acylsulfonium salts, obtained from β-(ethylsulfanyl)propionyl fluoride and (ethylsulfanyl)acetyl fluoride, with various unsaturated hydrocarbons proceed through the formation of six- and five-membered cyclic sulfonium salts, respectively. Succeeding cleavage of sulfonium salts by bases affords the corresponding sulfur containing unsaturated ketones.
  • Keywords
    ? , ?-Unsaturated ketones , Acylation , acylsulfonium salt , polyenones
  • Journal title
    Tetrahedron
  • Serial Year
    2001
  • Journal title
    Tetrahedron
  • Record number

    1082523