Title of article
Asymmetric induction in a new domino reaction of [3,3]-sigmatropic rearrangement of allylic thiocyanates and intramolecular heterocyclisation
Author/Authors
Jozef Gonda، نويسنده , , Miroslava Martinkov?، نويسنده , , Jan Imrich، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
6
From page
1611
To page
1616
Abstract
A new synthetic route to diastereomerically pure (4S,5S)-4-vinyltetrahydro-1H-2-imidazolethiones via a novel domino reaction of [3,3]-sigmatropic rearrangement of chiral thiocyanates followed by stereoselective intramolecular amine addition to arising isothiocyanates is reported.
Keywords
asymmetric induction , Aminoacids , rearrangements
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1082840
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