Title of article
Total synthesis of (±)-ceratopicanol
Author/Authors
Chisato Mukai، نويسنده , , Minoru Kobayashi، نويسنده , , In Jong Kim، نويسنده , , Miyoji Hanaoka، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
6
From page
5225
To page
5230
Abstract
Total synthesis of (±)-ceratopicanol () from commercially available 2-allyl-2-methylcyclopenta-1,3-dione () was completed. By taking advantage of the two carbonyl functionalities, was transformed into the enyne having an alkyne moiety, methyl substituent, and the hydroxy functionality with proper stereochemistry. The Pauson–Khand reaction of was followed by chemical modifications resulting in the alternative total synthesis of (±)-ceratopicanol ().
Keywords
(±)-ceratopicanol , triquinane sesquiterpene , Ceratocystis piceae
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083218
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