Title of article
SET photochemistry of phthalimide anion and its reactivity with hydrogen donors
Author/Authors
Cristobal S?nchez-S?nchez، نويسنده , , Ezequiel Pérez-Inestrosa، نويسنده , , Rafael Garc??a-Segura، نويسنده , , Rafael Suau، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
8
From page
7267
To page
7274
Abstract
The investigation of the photochemistry of phthalimide anion has uncovered its exceptional reactivity with hydrogen donors such as alcohols, toluene, ethers and amines. Photoreactions can be conducted to high conversions and photoadducts are formed in high yield and with predictable regioselectivity. Exploratory studies have revealed that SET from the excited phthalimide anion to phthalimide is a thermodinamically favourable step that produces the electrophilic phthalimidyl radical and is the key step of the process.
Keywords
Electron transfer , isoindoles , radicals and radical reactions , Photochemistry , Imides
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083428
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