Title of article
Group 5 and group 6 metal halides as very efficient catalysts for acylative cleavage of ethers
Author/Authors
Qiaoxia Guo، نويسنده , , Taichi Miyaji، نويسنده , , Ryuichiro Hara، نويسنده , , Baojian Shen، نويسنده , , Tamotsu Takahashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
8
From page
7327
To page
7334
Abstract
Group 5 and 6 metal chlorides such as MoCl5, WCl6, NbCl5 and TaCl5 were found as very efficient catalysts for acylative cleavage of the C–O bond of ethers. Compared with conventional Lewis acid catalysts such as ZnCl2, AlCl3, SnCl4 and TiCl4, group 5 and 6 metal chlorides showed better results in the catalytic C–O bond cleavage of dibutyl ether with benzoyl chloride.
Keywords
C–O bond cleavage , ether , Lewis acids
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083435
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