Title of article
Regioselectivity in the intramolecular allyl transfer reaction catalysed by electrogenerated nickel complexes: influence of metal ions
Author/Authors
Delphine Franco، نويسنده , , Elisabet Du?ach، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
8
From page
9289
To page
9296
Abstract
The intramolecular transfer of allyl moieties from substituted allyl aryl ethers to carbonyl groups has been studied by electrosynthesis, in a nickel-catalysed reaction. The influence of metal ions such as Mg2+, Zn2+ and Al3+ has been examined. Regioselectivity towards the branched isomer was better with Zn2+ than with Mg2+ ions, but it was higher in the absence of added metal ions.
Keywords
Regioselectivity , Electrochemical , Allylation , nickel , Metal ions
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083649
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