Title of article
Palladium-catalyzed hydrophenylation of bicyclic alkenes
Author/Authors
Peter Mayo، نويسنده , , William Tam، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
14
From page
9527
To page
9540
Abstract
Palladium-catalyzed hydrophenylation reactions of bicyclic alkenes were investigated. These reactions were found to be completely chemo- and stereoselective, giving only exo products on the less substituted double bonds of bicyclic alkenes in moderate to good yields. For unsymmetrical bicyclic alkenes, regioselectivities of 52:48 to 100:0 were observed with various substituents on the bicyclic alkenes.
Keywords
Palladium , bicyclic alkenes , Stereoselectivity , Chemoselectivity , Regioselectivity , hydrophenylation , Heck coupling
Journal title
Tetrahedron
Serial Year
2002
Journal title
Tetrahedron
Record number
1083667
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