Title of article
Synthesis and reactivity of lithium tri(quinolinyl)magnesates
Author/Authors
Sylvain Dumouchel، نويسنده , , Florence Mongin، نويسنده , , François Trécourt، نويسنده , , Guy Queguiner، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
12
From page
8629
To page
8640
Abstract
2-, 3- and 4-Bromoquinolines were converted to the corresponding lithium tri(quinolinyl)magnesates at −10°C when exposed to Bu3MgLi in THF. The resulting organomagnesium derivatives were quenched with various electrophiles or involved in metal-catalyzed coupling reactions with heteroaryl halides to afford functionalized quinolines.
Keywords
in situ IR , Quinolines , ate complexes , Cross-coupling
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084417
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