• Title of article

    Synthesis and reactivity of lithium tri(quinolinyl)magnesates

  • Author/Authors

    Sylvain Dumouchel، نويسنده , , Florence Mongin، نويسنده , , François Trécourt، نويسنده , , Guy Queguiner، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    12
  • From page
    8629
  • To page
    8640
  • Abstract
    2-, 3- and 4-Bromoquinolines were converted to the corresponding lithium tri(quinolinyl)magnesates at −10°C when exposed to Bu3MgLi in THF. The resulting organomagnesium derivatives were quenched with various electrophiles or involved in metal-catalyzed coupling reactions with heteroaryl halides to afford functionalized quinolines.
  • Keywords
    in situ IR , Quinolines , ate complexes , Cross-coupling
  • Journal title
    Tetrahedron
  • Serial Year
    2003
  • Journal title
    Tetrahedron
  • Record number

    1084417