Title of article
A two step synthesis of 2-oxo-2-vinyl 1,3,2-dioxaphospholanes and -dioxaphosphorinanes
Author/Authors
Michel Maffei، نويسنده , , Gérard Buono، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
8821
To page
8825
Abstract
The title compounds are prepared via a two step procedure involving a transesterification between a diol and diethyl phosphite followed by a palladium-catalyzed coupling of the so-obtained cyclic phosphite with vinyl bromide. Theoretical DFT calculations have been performed on phosphonate and phosphite anions models in order to estimate stereoelectronic effects in five-membered and six-membered ring compounds.
Keywords
2-oxo-2-vinyl 1 , 3 , 2-oxo-2-vinyl 1 , 2-dioxaphospholanes , 3 , vinyl bromide , Palladium , Transesterification , DFT calculations , 2-dioxaphosphorinanes
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1084432
Link To Document