Title of article
An intramolecular oxo Diels–Alder approach to 1-oxo-1,2,3,3a,4,7a-hexahydro-pyrano[3,4-c]pyrrole-4-carboxylic acid ethyl esters
Author/Authors
William V Murray، نويسنده , , Pranab K Mishra، نويسنده , , Ignatius J. Turchi، نويسنده , , Dorota Sawicka، نويسنده , , Amy Maden، نويسنده , , Sengen Sun، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
7
From page
8955
To page
8961
Abstract
The diastereoselective synthesis of a series of 1-oxo-1,2,3,3a,4,7a-hexahydro-pyrano[3,4-c]pyrrole-4-carboxylic acid ethyl esters via an oxo Diels–Alder reaction is described. Ab initio calculations predicted the products of the exo cycloaddition to be the thermodynamic products while the products resulting from the endo cycloaddition were predicted to be the kinetic products. The calculations were born out by experimental data.
Keywords
Diels–Alder , pyrrolidine templates , Diastereoselective synthesis
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1084446
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