• Title of article

    Metalated epoxides as carbenoids. Competing C–H and CC insertion in α-alkoxy epoxide systems

  • Author/Authors

    Luc Dechoux، نويسنده , , Claude Agami، نويسنده , , Eric Doris، نويسنده , , Charles Mioskowski، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    6
  • From page
    9701
  • To page
    9706
  • Abstract
    In a reinvestigation of the reactivity of carbenoids derived from epoxides, we studied the factors that could influence the chemoselectivity of the carbenoid insertion into vicinal C–H or CC bond in cyclic α-alkoxy epoxides bearing an alkenyl side chain. This reaction gives access to bi- or tricyclic systems, respectively.
  • Keywords
    Cyclopropanes , Cycloaddition , Epoxides , Insertion , carbenoids
  • Journal title
    Tetrahedron
  • Serial Year
    2003
  • Journal title
    Tetrahedron
  • Record number

    1084518