Title of article
Oxidative free radical reactions of enamino esters
Author/Authors
Che-Ping Chuang، نويسنده , , Yi-Lung Wu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
7
From page
1841
To page
1847
Abstract
Oxidative free radical reactions of enamino esters are described. Electrophilic carbon-centered radicals produced by the cerium(IV) ammonium nitrate (CAN) oxidation of β-dicarbonyl compounds undergo efficient addition to the C–C double bond of enamino esters. This CAN mediated free radical reaction between enamino esters and β-dicarbonyl compounds provides a novel method for the synthesis of highly substituted pyrroles. The direct CAN oxidation of β-enaminocinnamates gave the dimerization products effectively.
Keywords
Enamino esters , cerium(IV) ammonium nitrate , Free radical , oxidative
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1084939
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