Title of article
Fast diastereoselective Baylis–Hillman reaction by nitroalkenes: synthesis of di- and triene derivatives
Author/Authors
Roberto Ballini، نويسنده , , Luciano Barboni، نويسنده , , Giovanna Bosica، نويسنده , , Dennis Fiorini، نويسنده , , Emanuela Mignini، نويسنده , , Alessandro Palmieri، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
4995
To page
4999
Abstract
The Baylis–Hillman reaction is performed using nitroalkenes as activated alkenes, ethyl-2-bromomethylacrylate as electrophilic acceptor and DBU as catalyst base. Nitro dienes are obtained in good yields and very short reaction times. Moreover, starting from appropriate nitroalkenes it is possible to realize one pot the synthesis of trienic systems.
Keywords
Baylis–Hillman reaction , Nitroalkenes , Nitro dienes , Allylic nitro compounds , Michael reaction
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1085648
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