Title of article
Inverse electron-demand aza-[4+2] cycloaddition reactions of allenamides
Author/Authors
Craig R. Berry، نويسنده , , Richard P. Hsung، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
8
From page
7629
To page
7636
Abstract
An inverse electron-demand aza-[4+2] cycloaddition reaction of allenamides with 1-azadiene is described here. Effects of solvents on diastereoselectivity along with synthetic scopes and mechanistic insights are illustrated. Despite some synthetic limitations, this aza-[4+2] cycloaddition does provide a useful template for the synthesis of aza-glycoside related heterocycles.
Keywords
allenamides , Diels–Alder , Cycloaddition , Inverse Demand , 1-azadiene , Aza-glycoside
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1086985
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