Title of article
Functional rearrangement of polychlorinated pyrrolidin-2-ones to 5-imino-lactams promoted by n-propylamine
Author/Authors
Chiara Danieli، نويسنده , , Franco Ghelfi، نويسنده , , Adele Mucci، نويسنده , , Ugo M. Pagnoni، نويسنده , , Andrew F. Parsons، نويسنده , , Mariella Pattarozzi، نويسنده , , Luisa Schenetti، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
9
From page
11493
To page
11501
Abstract
The reaction of 4-methyl-pyrrolidin-2-ones, chlorinated at the C(3) and C(6) positions, with n-propylamine constitutes a new method for the preparation of 5-propylimino-pyrrolidin-2-ones or 3-pyrrolin-2-ones in generally good yields. The transformation involves a series of eliminations, substitutions and double bond shifts. This constitutes a remarkable example of a functional rearrangement.
Keywords
Radical reactions , pyrrolidinones , rearrangements , N-Nucleophiles
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1087366
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