Title of article
Conditions for deuterium exchange mediated by iridium complexes formed in situ
Author/Authors
Paul W.C Cross، نويسنده , , George J Ellames، نويسنده , , Jennifer S Gibson، نويسنده , , John H. Herbert، نويسنده , , William J Kerr، نويسنده , , Alan H McNeill، نويسنده , , Trevor W Mathers، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
10
From page
3349
To page
3358
Abstract
A series of iridium-based complexes formed in situ, containing pyridine, phosphines, triphenylarsine, triphenylstibine, and triphenylamine as ligands, has been screened for ability to mediate ortho-exchange of hydrogen in a series of model substrates. Improved incorporation into a number of substrate classes has been achieved. The electronic properties and number of ligands at the metal centre are instrumental in determining which catalysts are best suited to exchange in any given substrate.
Keywords
deuterium exchange , isotope exchange , iridium complexes
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087749
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