• Title of article

    Platinum-catalyzed highly selective thiocarbonylation of acetylenes with thiols and carbon monoxide

  • Author/Authors

    Junichi Kawakami، نويسنده , , Masanori Mihara، نويسنده , , Ikuyo Kamiya، نويسنده , , Mitsuhiro Takeba، نويسنده , , Akiya Ogawa، نويسنده , , Noboru Sonoda، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    6
  • From page
    3521
  • To page
    3526
  • Abstract
    A novel carbonylative addition of thiols (RSH) to terminal acetylenes (R′–CCH) takes place successfully in the presence of platinum catalysts under the pressure of carbon monoxide, providing α,β-unsaturated thioesters (R′–C(C(O)SR)CH2) in good yields regioselectively. This ‘hydrothiocarbonylation’ reaction of acetylenes may include the formation of the platinum sulfide complex as key species.
  • Keywords
    thiocarbonylation , Platinum , Carbon monoxide , Thiols , acetylenes
  • Journal title
    Tetrahedron
  • Serial Year
    2003
  • Journal title
    Tetrahedron
  • Record number

    1087771

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1087771