Title of article
Oxidative radical cyclization on enamide systems using n-Bu3SnH and dilauroyl peroxide
Author/Authors
Miguel A. Guerrero، نويسنده , , Raymundo Cruz-Almanza، نويسنده , , Luis D. Miranda، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
6
From page
4953
To page
4958
Abstract
Efficient 5-endo and 6-endo oxidative radical cyclizations on enamide systems are described using nBu3SnH and dilauroyl peroxide both as initiator and oxidant. Dibenzoyl peroxide and dicumyl peroxide were also tested in the same reaction and the product yields were very similar to those obtained with dilauroyl peroxide. The erythrina ring system was constructed in a two-step sequence featuring this novel process.
Keywords
Oxidation , enamide , erythrina , Radical cyclization , dilauroyl peroxide
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087919
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