Title of article
New polymers for catalytic carbene transfer: electropolymerization of tetrafluorenylporphyrinruthenium carbon monoxide
Author/Authors
Christine Paul-Roth، نويسنده , , Joelle Rault-Berthelot، نويسنده , , Gérard Simonneaux، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
7
From page
12169
To page
12175
Abstract
Condensation of pyrrole with 2-fluorenecarboxaldehyde yields meso-tetrafluorenylporphyrin as a new building block. After ruthenium insertion, oxidative electropolymerization of tetrafluorenylporphyrinruthenium (II) carbonyl complexes can be used to coat Pt electrodes with polymeric films. These insoluble polymeric materials are able to catalyze the heterogeneous cyclopropanations and 2,3 sigmatropic rearrangements with ethyl diazoacetate after being removed from the electrode.
Keywords
Porphyrins , Ruthenium , Fluorene , Electropolymerization , Catalysis , Polymers
Journal title
Tetrahedron
Serial Year
2004
Journal title
Tetrahedron
Record number
1088212
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