• Title of article

    Constructing the CF3 group; unique trifluorodecarboxylation induced by BrF3

  • Author/Authors

    Revital Sasson، نويسنده , , Shlomo Rozen، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    4
  • From page
    1083
  • To page
    1086
  • Abstract
    A variety of 2-alkyl-1,3-dithiane-2-carboxylic acids was prepared from the appropriate alkyl halides, 1,3-dithiane and CO2. These acids were reacted with BrF3 to form the trifluoromethylalkyl derivatives via a combination of ionic and radical trifluorodecarboxylation in about 50–60% yield.
  • Keywords
    Trifluoromethyl , Trifluorodecarboxylation , Bromine trifluoride , Dithiane
  • Journal title
    Tetrahedron
  • Serial Year
    2005
  • Journal title
    Tetrahedron
  • Record number

    1088331