Title of article
Constructing the CF3 group; unique trifluorodecarboxylation induced by BrF3
Author/Authors
Revital Sasson، نويسنده , , Shlomo Rozen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
1083
To page
1086
Abstract
A variety of 2-alkyl-1,3-dithiane-2-carboxylic acids was prepared from the appropriate alkyl halides, 1,3-dithiane and CO2. These acids were reacted with BrF3 to form the trifluoromethylalkyl derivatives via a combination of ionic and radical trifluorodecarboxylation in about 50–60% yield.
Keywords
Trifluoromethyl , Trifluorodecarboxylation , Bromine trifluoride , Dithiane
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088331
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