Title of article
An efficient method for the synthesis of methyl 11α-amino-3α,7α-diacetoxy-12-oxo-5β-cholan-24-oate
Author/Authors
Deepak B. Salunke، نويسنده , , Braja G. Hazra، نويسنده , , Rajesh G. Gonnade، نويسنده , , Mohan M. Bhadbhade، نويسنده , , Vandana S. Pore، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
8
From page
3605
To page
3612
Abstract
The synthesis of methyl 11α-azido-3α,7α-diacetoxy-12-oxo-5β-cholan-24-oate, methyl 11β-azido-3α,7α-diacetoxy-12-oxo-5β-cholan-24-oate and methyl 11α-amino-3α,7α-diacetoxy-12-oxo-5β-cholan-24-oate have been achieved. Mechanistic aspects for the decomposition of steroidal azidoketones to its enamines are discussed.
Keywords
11-Azidosteroid , 11-Aminosteroid , HIV-1 protease inhibitors , Steroidal enamines , Base catalyzed epimerization
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088582
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