Title of article
Intermolecular reductive coupling of hindered N-aryl imines towards the modular synthesis of chiral N-heterocyclic carbenes
Author/Authors
Gregory J. Mercer، نويسنده , , Megan Sturdy، نويسنده , , David R. Jensen، نويسنده , , Matthew S. Sigman، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
7
From page
6418
To page
6424
Abstract
We describe a simple method for the synthesis of hindered N-aryl diamines. The diastereoselectivity for these processes are relatively low but the diamines can be separated using either chromatography or selective crystallization. Separation of enantiomers can be accomplished using HPLC equipped with a chiral stationary phase.
Keywords
N-Aryl , cross coupling , reductive coupling
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088856
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