Title of article
Metallation of pyridin-2-yldiazines. Use of pyridine ring as ortho-directing group. Diazines. Part 45
Author/Authors
Camelia Berghian، نويسنده , , Mircea Darabantu، نويسنده , , Alain Turck، نويسنده , , Nelly Plé، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
8
From page
9637
To page
9644
Abstract
Starting from commercial chlorodiazines, we report the synthesis of pyridin-2-yldiazines. The first lithiation and functionalization of these compounds are reported and the regioselectivity of the metallation is discussed. The functionalization via the metallation reaction, provides a new access to substituted pyridin-2-yldiazines, which could be used as building blocks in supramolecules.
Keywords
metallation , Functionalization , ortho-directing group , Pyridin-2-yldiazines
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1089195
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