Title of article
Preparation of 15-membered unsaturated N–H containing azamacrocycles and their differential coordination with Pd(0) and Pd(II)
Author/Authors
Judit Masllorens، نويسنده , , Marcial Moreno-Ma?as، نويسنده , , Anna Roglans، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
8
From page
10105
To page
10112
Abstract
The use of 2-(trimethylsilylethyl)sulfonamide (SES-NH2) has permitted the selective and efficient synthesis of new triolefinic 15-membered azamacrocycles . Differential coordination mode with palladium has been observed when macrocycle [(E,E,E)-1,6-bis(p-tolylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene] was treated with a palladium(0) or a palladium(II) source.
Keywords
Macrocycles , Azamacrocycles , Sulfonamides , Protecting groups , Palladium
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1089246
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