• Title of article

    Synthesis of (−)-(5R,6S)-6-acetoxyhexadecanolide based on l-proline-catalyzed asymmetric aldol reactions

  • Author/Authors

    Hideaki Ikishima، نويسنده , , Yusuke Sekiguchi، نويسنده , , Yoshiyasu Ichikawa، نويسنده , , Hiyoshizo Kotsuki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    6
  • From page
    311
  • To page
    316
  • Abstract
    A convenient method for proline-catalyzed asymmetric aldol reactions using synthons of straight-chain aliphatic aldehydes, and aldehydes bearing a 1,3-dithiane moiety at the β-position, has been developed. This method was successfully applied to the synthesis of (−)-(5R,6S)-6-acetoxyhexadecanolide, an oviposition attractant pheromone of the female Culex mosquito.
  • Keywords
    proline , Aldehydes , Oviposition attractant pheromone , aldol
  • Journal title
    Tetrahedron
  • Serial Year
    2006
  • Journal title
    Tetrahedron
  • Record number

    1089494