Title of article
Stereoselective preparation of trifluoromethyl containing 1,4-oxathiolane derivatives through ring expansion reaction of 1,3-oxathiolanes
Author/Authors
Shifa Zhu، نويسنده , , Chunhui Xing، نويسنده , , Shizheng Zhu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
829
To page
832
Abstract
Trifluoromethyl containing 1,4-oxathiolanes are synthesized in excellent yields and high stereoselectivities from the expansion reactions of sulfur ylide intermediates, which were prepared from the reaction of 2-diazo-3,3,3-trifluoro-propionic acid methyl ester and 1,3-oxathiolanes in the presence of Rh2(OAc)4.
Keywords
Diastereomeric ratio , Lipophilicity , Sulfur ylide , diazo , 4-Oxathiolane , 1 , Trifluoromethyl , Stereoselective synthesis
Journal title
Tetrahedron
Serial Year
2006
Journal title
Tetrahedron
Record number
1089546
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