Title of article
A one-pot access to cycloalkano[1,2-a]indoles through an intramolecular alkyl migration reaction in indolylborates
Author/Authors
Minoru Ishikura، نويسنده , , Wataru Ida، نويسنده , , Kazuo Yanada، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
10
From page
1015
To page
1024
Abstract
A novel one-pot protocol for the preparation of cycloalkano[1,2-a]indoles by way of an intramolecular alkyl migration reaction in cyclic indolylborates is described. NaOMe was found to act as a successful trialkylboryl-protecting group against to the lithiation at the C2 of the indole ring. Treatment of cyclic indolylborates with electrophiles produced cycloalkano-[1,2-a]indoles.
Keywords
Hydroboration , intramolecular alkyl migration , Cyclic indolylborate
Journal title
Tetrahedron
Serial Year
2006
Journal title
Tetrahedron
Record number
1089570
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