• Title of article

    Regioselective electrophilic substitutions of fulvenes with ethyl glyoxylate and subsequent Diels–Alder reactions

  • Author/Authors

    Hsing-Chang Tseng، نويسنده , , Arun Kumar Gupta، نويسنده , , Bor-Cherng Hong، نويسنده , , Ju-Hsiou Liao، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    8
  • From page
    1425
  • To page
    1432
  • Abstract
    Highly regioselective electrophilic substitution of fulvenes with ethyl glyoxylate, catalyzed by EtAlCl2 or Yb(OTf)3 was achieved. Subsequent Diels–Alder reaction of the adduct with various dienophiles provides an efficient protocol toward highly functionalized indane and tricyclo[5.2.1.02,6]dec-8-ene systems.
  • Keywords
    fulvene , Diels–Alder , Cycloaddition , Catalysis , Friedel–Craft
  • Journal title
    Tetrahedron
  • Serial Year
    2006
  • Journal title
    Tetrahedron
  • Record number

    1089615