Title of article
Synthesis of highly substituted pyrroles via oxidative free radical reactions of β-aminocinnamates
Author/Authors
An-I Tsai، نويسنده , , Che-Ping Chuang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
2235
To page
2239
Abstract
Oxidative free radical reactions of β-aminocinnamates are described. Imine radicals produced by tetra-n-butylammonium cerium(IV) nitrate (TBACN) oxidation of enamines undergo efficient addition to the C–C double bond of β-aminocinnamates. This TBACN mediated free radical reaction between β-aminocinnamates and enamines provides a novel method for the synthesis of highly substituted pyrroles. The direct TBACN oxidation of β-aminocinnamates gave the dimerization products effectively.
Keywords
?-Aminocinnamates , Tetra-n-butylammonium cerium(IV) nitrate , oxidative , Free radical
Journal title
Tetrahedron
Serial Year
2006
Journal title
Tetrahedron
Record number
1089702
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