Effect of sliding speed on friction and wear behaviour of nanocrystalline nickel tested in an argon atmosphere

The sliding speed dependence of the coefficient of friction (COF) and wear rate (W) of a nanocrystalline (nc) Ni with a grain size of 15 ± 3 nm and a hardness of 5.09 ± 0.11 GPa was compared to that of a microcrystalline (mc) Ni with a grain size of 20 ± 5 μm and a hardness of 1.20 ± 0.05 GPa. The sliding wear tests were performed in an argon environment under a constant normal load of 2 N using three different sliding speeds of 0.2 × 10−2, 0.8 × 10−2 and 3.0 × 10−2 m/s. The lesser wear damage in the nc Ni at any given speed was attributed to its higher hardness and its greater elastic depth recovery ratio compared to the mc Ni. The mc Niʹs COFs and wear rates were independent of the sliding speed over the relatively small range used. However, the same small increase in sliding speed caused an 86% reduction in the nc Niʹs wear rate, from 3.44 × 10−3 to 0.47 × 10−3 mm3/m, and a 31% increase in its COF, from 0.49 ± 0.05 to 0.64 ± 0.06. A modified Archard equation was proposed to predict wear rates of Ni as a function of grain size and sliding speed. Increasing the sliding speed made it increasingly difficult for surface damage by plastic deformation to occur in the nc Ni, because the grain-boundary-induced deformation mechanisms are more difficult to operate at higher strain rates. At the highest speed, the smallest amount of debris was generated, which was not sufficient to form protective tribolayers leading to a high COF value.