Title of article
Total synthesis of (−)-elegansidiol by using an abnormal Beckmann fragmentation of Hajos ketone oxime as a key step
Author/Authors
Liya Cao، نويسنده , , Jianwei Sun، نويسنده , , Xinyan Wang، نويسنده , , Rui Zhu، نويسنده , , Haijian Shi، نويسنده , , Yuefei Hu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
6
From page
5036
To page
5041
Abstract
Abnormal Beckmann fragmentation of Hajos ketone oxime regioselectively forms of a chiral 1-oxygenated 2,2-dimethyl-4-methylene-cyclohexan skeleton. Using this transformation as a key step, the total synthesis of (−)-elegansidiol, an oxygenated mono-carbocyclic sesquiterpenoid, was achieved.
Keywords
Total synthesis , (?)-Elegansidiol , Abnormal Beckmann fragmentation , Hajos ketone
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1090888
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