Title of article
On the scope of diastereoselective allylation of various chiral glyoxylic oxime ethers with allyltributylstannane in the presence of a Lewis acid and triallylaluminum
Author/Authors
Neelesh A. Kulkarni، نويسنده , , Ching-Fa Yao، نويسنده , , Kwunmin Chen، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
7
From page
7816
To page
7822
Abstract
The nucleophilic allylation of various chiral auxiliaries derived glyoxylic oxime ethers was studied. The use of allyltributylstannane in the presence of a Lewis acid and triallylaluminum provided the corresponding homoallylic amines in high chemical yields (up to 89%) and excellent stereoselectivities (up to >99%). The stereochemical bias of the allylation is proposed.
Keywords
Allylation , Glyoxylic oxime ether , Chiral auxiliary , Triallylaluminum
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1091385
Link To Document